Product ID:1,1,1, TRICHLOROETHANE
MSDS Date:12/30/1986
FSC:6810
NIIN:00-476-5612
MSDS Number: BGVRT

CSD INC.

5 HACKBERRY LANE
CUT & SHOOT, TX 77302
US

Emergency Phone: 704-821-9822

Info Phone: 704-821-9822

Cage: JO933

CSD INC.

687 CONROE, TX 77305 US

Telephone: 409-756-1065

Cage: JO933

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 90-95%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III)

CAS: 123-91-1

RTECS: JG8225000

OSHA PEL S, 100 PPM

ACGIH TLV: S, 25 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT) = 10300 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:SKIN,CENTRAL NERVOUS
SYSTEM,CARDIO VASCULAR SYSTEM AND EYES.SEE ALSO SIGNS AND SYMPTOMS
OF OVEREXPOSURE.
Explanation of Carcinogenicity:CONTAINS DIETHYLENE ETHER(1,4-DIOXANE).
1,4-DIOXANE LISTED BY NTP AND IARC AS AN ANIMAL CARCINOGEN 11,4-D.
Effects of Overexposure:EYES/SKIN:IRRITATION. SYSTEMIC
EFFECTS:RESPIRATORY TRACT IRRITATION,ANESTHESIA IN HIGH
CONCENTRATIONS,NAUSEA AND VOMITING,DIARRHEA AND ABDOMINAL
PAIN,CANCER IN ANIMALS.
Medical Cond Aggravated by Exposure:INCREASED SENSITIVITY TO ADRENALIN
MAY BE CAUSED BY OVER EXPOSURE.

First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR 15 MINUTES.SEE DOCTOR.
SKIN:REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE
OXYGEN/CPR IF NEEDED.SEE DOCT0R. INGESTION:SEE
DOCTORIMMEDIATELY.--NEVER ADMINISTER ADRENALINE--

Flash Point:NONE
Lower Limits:6.3
Upper Limits:15.5
Fire Fighting Procedures:SCBA SHOULD BE USED BY FIREMEN IN BUILDING
WHERE 1,1,1, TRICHLOROETHANE IS STORED. KEEP CONTAINER COOL.
Unusual Fire/Explosion Hazard:VAPORS CAN BE IGNITED BY HIGH ENERGY
IGNITION SOURCE.DECOMPOSES WITH FIRE OR HOT SURFACES TO ACIDIC
GASES AND OTHER HIGHLY TOXIC SUBSTANCES.

Spill Release Procedures:SMALL SPILL: WIPE UP WITH RAGS OR TOWELS.
LARGE SPILLS: WEAR NIOSH APPROVED RESPIRATOR. VENTILATE AREA. DIKE
TO RETAIN FLUID. PUMP UP FREE LIQUID. RESIDUE WILL EVAPORATE
QUICKLY. DO NOT FLUSH TO SEWER OR WATERWAY.
Neutralizing Agent:NONE

Handling and Storage Precautions:AVOID CONTACT WITH SKIN AND AVOID
VAPORS. PIPE VENTS OUTDOORS. STORE IN COOL, DRY VENTILATED AREA.
Other Precautions:PREVENT MOIST AIR FROM ENTERING STORAGE AREA.NO
SMOKING IN PRESENCE OF VAPORS.

Respiratory Protection:NONE REQUIRED WHEN USED WITH ADEQUATE
VENTILATION.
Ventilation:SUFFICIENT LOCAL EXHAUST VENTILATION TO MAINTAIN EXPOSURE
BELOW TLV.
Protective Gloves:PVC,NEOPRENE,VITON.
Eye Protection:SAFETY GOGGLES.
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING TOILET FACILITIES. DO NOT BREATH VAPORS OR MIST.
Supplemental Safety and Health
TARGET ORGANS ARE SKIN, CNS, CVS, AND EYES

HCC:T4
Boiling Pt:B.P. Text:162F(72C)
Melt/Freeze Pt:M.P/F.P Text:-36F(FZ PT)
Vapor Pres:100
Vapor Density:4.6
Spec Gravity:1.3
Evaporation Rate & Reference:0.4 (ETHER = 1)
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS CLEAR LIQUID.MILDLY SWEET ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:CONTACT WITH OPEN FLAME, HOT SURFACES OR
EMISSIONS FROM WELDING ARC.
Hazardous Decomposition Products:HYDROGEN CHLORIDE,PHOSGENE AND OTHER
HIGHLY TOXIC SUBSTANCES.

Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL
REGULATIONS

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.